Reigning champion Amelie Mauresmo was an easy winner, while Australian Open titlist Serena Williams and U.S. and French Open runner-up Elena Dementieva bowed out in second-round action Wednesday at the $1.3 million Italian Masters.
Heavy Italian crowd favorite Francesca Schiavone stunned the third-seeded Williams 7-6 (7-2), 6-1 in 1 hour, 22 minutes on the red clay at Foro Italico.
Schiavone beat Williams for the first time in three meetings. They hadn't met since 2003.
A rusty seven-time Grand Slam champion Williams, who received an opening-round bye, was playing her first tennis in a month after nursing an ankle injury and dropped to 2-3 in her last five outings. She hasn't reached a final since titling in Melbourne back in January.
Williams captured the Italian Open in 2002.
The second-seeded Mauresmo, seeking her fifth trip to the final here in the last six years, ripped through Aussie Samantha Stosur 6-2, 6-0.
Mauresmo beat American Jennifer Capriati in last year's Rome final and was the runner-up in 2000, 2001 and 2003. Her opponent on Thursday will be veteran Italian Silvia Farina Elia.
Capable Argentine Gisela Dulko toppled the fourth-seeded Dementieva 7-5, 6-4. Dementieva was the only woman to reach two Grand Slam finals last season.
Three other seeded Russians avoided upsets on Day 3, as No. 6 Vera Zvonareva zipped past rising Serb Jelena Jankovic 6-4, 6-1, No. 7 Nadia Petrova pasted Italian Mara Santangelo 6-3, 6-1 and No. 9 Elena Bovina handled Italian Roberta Vinci 7-5, 6-2.
Eighth-seeded Swiss Patty Schnyder moved on by dismissing German Anna-Lena Groenefeld 6-2, 6-4, while a 13th-seeded Farina Elia defeated France's Stephanie Cohen-Aloro 6-3, 6-3 and 15th-seeded Japanese Ai Sugiyama blasted Venezuelan Maria Vento-Kabchi 6-3, 6-0.
Former Rome champion Mary Pierce snuck past Croat Sanda Mamic 6-4, 6-4, while four-time titlist Conchita Martinez came back to beat Israeli Anna Smashnova 3-6, 6-1, 6-1. Pierce won this event in 1997 and was the runner-up in 1999, while Martinez captured the tournament from 1993-96 and lost to Pierce in the '97 final.
Pierce's third-round opponent will be top-seeded Russian Maria Sharapova, who could supplant American Lindsay Davenport atop the WTA Tour rankings with a title this week.
Other second-round wins came for Russian Evgenia Linetskaya, Serb Ana Ivanovic and Colombian Catalina Castano.
The 2005 Rome titlist will collect $189,000.